
AFM: Dynamic pH regulation and interfacial ion redistribution of dendrite-free zinc metal anodes via molecular buffering
AFM: Dynamic pH regulation and interfacial ion redistribution of dendrite-free zinc metal anodes via molecular buffering Reference link: https://doi.org/10.1002/adfm.202514260 Research Overview Aqueous zinc-ion batteries (Zn-ion batteries) suffer from irreversible anode performance degradation caused by electrolyte alkalinization and uneven Zn deposition driven by the hydrogen evolution reaction (HER). This study proposes a bifunctional buffer additive that synergistically combines pH regulation and interfacial ion redistribution. This buffer additive maintains a self-regulated electrolyte pH (≈3) through a proton donor-acceptor equilibrium, effectively scavenging hydroxyl ions to prevent Zn passivation. It also induces preferential adsorption of Na⁺ on protrusions, promoting planar Zn deposition through a charge screening effect. This dual mechanism enables Cu-Zn half-cells to




