
All-solid-state sodium-ion batteries operating at room temperature
All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi2(PO4)3 cathode and ceramic NASICON solid electrolyte: A complete in situ synchrotron X-ray study Highlights •NASICON-type NaTi2(PO4)3/C is developed as cathode for sodium-ion battery. •Solid-state electrolyte Na3.16Zr1.84Y0.16Si2PO12 is prepared. •Prepared All-solid-state sodium-ion battery works at room temperature. •The in situ synchrotron X-ray study shows the bi-phasic reaction of cathode. •Sequential Rietveld refinements are analyzed to understand the phase evolution. Abstract All-solid-state sodium-ion batteries that work at ambient temperature are a potential approach for large-scale energy storage systems. Nowadays, ceramic solid electrolytes are gaining attention because of their good ionic conductivity and excellent mechanical and chemical stabilities. Furthermore, a





