
Analysis of Capacity Fade Mechanisms in Lithium-ion Batteries 2026
Degradation Factors Specific Mechanisms Key Data / Observations Mitigation Strategies Reference Cathode Failure Phase transition of layered structures (e.g., NCM) Capacity loss increases by 20% after 100 cycles at 4.6V Single-crystal cathodes; Surface coating (Li3PO4) Jung et al., 2017 Jahn-Teller distortion in LiMn2O4 6.5% volume expansion; crack density triples after 50 cycles Voltage window limitation (3.0-4.3V) Thackeray et al., 1998 Anode SEI Growth Thickening of SEI on graphite Interfacial impedance triples at 60 Celsius Film-forming additives (VC, FEC) Vetter et al., 2005 Volume expansion of silicon anodes 40% pulverization rate for 150nm Si particles after 50 cycles Nanosizing (under 50nm); Pre-lithiation Chan et al., 2008 Electrolyte Decomposition LiPF6 hydrolysis generating





